From pyrroles to 1-oxo-2,3,4,9-tetrahydro-1H-beta-carbolines: a new class of orally bioavailable mGluR1 antagonists

Bioorg Med Chem Lett. 2007 Apr 15;17(8):2254-9. doi: 10.1016/j.bmcl.2007.01.055. Epub 2007 Jan 25.

Abstract

Exploiting the SAR of the known pyrrole derivatives, a new class of mGluR1 antagonists was designed by replacement of the pyrrole core with an indole scaffold and consequent cyclization of the C-2 position into a tricyclic beta-carboline template. The appropriate exploration of the position C-6 with a combination of H-bond acceptor groups coupled with bulky/lipophilic moieties led to the discovery of a new series of mGluR1 antagonists. These compounds exhibited a non-competitive behavior, excellent pharmacokinetic properties, and good in vivo activity in animal models of acute and chronic pain, after oral administration.

MeSH terms

  • Administration, Oral
  • Analgesics / chemical synthesis
  • Analgesics / pharmacology
  • Animals
  • Carbolines / chemical synthesis*
  • Carbolines / pharmacokinetics*
  • Carbolines / therapeutic use
  • Disease Models, Animal
  • Drug Design
  • Excitatory Amino Acid Antagonists / chemical synthesis*
  • Excitatory Amino Acid Antagonists / pharmacokinetics
  • Excitatory Amino Acid Antagonists / therapeutic use
  • Humans
  • Inhibitory Concentration 50
  • Ligands
  • Mice
  • Pain / drug therapy*
  • Receptors, Metabotropic Glutamate / antagonists & inhibitors*
  • Structure-Activity Relationship

Substances

  • Analgesics
  • Carbolines
  • Excitatory Amino Acid Antagonists
  • Ligands
  • Receptors, Metabotropic Glutamate
  • metabotropic glutamate receptor type 1