Synthesis and preliminary evaluation of 18F- or 11C-labeled bicyclic nucleoside analogues as potential probes for imaging varicella-zoster virus thymidine kinase gene expression using positron emission tomography

J Med Chem. 2007 Mar 8;50(5):1041-9. doi: 10.1021/jm060964m. Epub 2007 Feb 14.

Abstract

Two radiolabeled bicyclic nucleoside analogues (BCNAs) were synthesized, namely 3-(2'-deoxy-beta-d-ribofuranosyl)-6-(3-[18F]fluoroethoxyphenyl)-2,3-dihydrofuro[2,3-d]pyrimidin-2-one ([18F]-2) and 3-(2'-deoxy-beta-d-ribofuranosyl)-6-(3-[11C]methoxyphenyl)-2,3-dihydrofuro[2,3-d]pyrimidin-2-one ([11C]-3), and evaluated as PET reporter probes for varicella-zoster virus thymidine kinase (VZV-tk) gene expression imaging in brain. [18F]-2 and [11C]-3 were synthesized starting from phenol precursor 1. The phenol precursor 1 was converted to stable as well as to radiolabeled compounds 2 and 3 using (19/18)FCH(2)CH(2)Br or (12/11)CH(3)I as alkylating agent. In vitro evaluation of [18F]-2 and [11C]-3 in 293T cells showed a 4.5 and 53-fold higher uptake, respectively, into VZV-tk gene-transduced cells compared to control cells. However, biodistribution studies in mice demonstrated low uptake of these tracers in the brain. RP-HPLC analysis of plasma and urine samples of mice injected with [11C]-3 revealed that this tracer is very stable in vivo. These data warrant further evaluation of these tracers as noninvasive imaging agents for VZV infection and VZV-tk reporter gene expression in vivo.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Brain / diagnostic imaging*
  • Brain / enzymology*
  • Carbon Radioisotopes
  • Cell Line
  • Chromatography, High Pressure Liquid
  • Fluorine Radioisotopes
  • Gene Expression
  • Herpesvirus 3, Human / enzymology*
  • Humans
  • Male
  • Mice
  • Positron-Emission Tomography
  • Pyrimidine Nucleosides / chemical synthesis*
  • Pyrimidine Nucleosides / chemistry
  • Pyrimidine Nucleosides / pharmacokinetics
  • Radiopharmaceuticals / chemical synthesis*
  • Radiopharmaceuticals / chemistry
  • Radiopharmaceuticals / pharmacokinetics
  • Thymidine Kinase / biosynthesis*
  • Thymidine Kinase / genetics
  • Tissue Distribution

Substances

  • 3-(2'-deoxyribofuranosyl)-6-(3-fluoroethoxyphenyl)-2,3-dihydrofuro(2,3-d)pyrimidin-2-one
  • 3-(2'-deoxyribofuranosyl)-6-(3-methoxyphenyl)-2,3-dihydrofuro(2,3-d)pyrimidin-2-one
  • Carbon Radioisotopes
  • Fluorine Radioisotopes
  • Pyrimidine Nucleosides
  • Radiopharmaceuticals
  • Thymidine Kinase