Linkage isomerism in a face-centered cubic Cu6Cr8(CN)24 cluster with an S=15 ground state

T David Harris; Jeffrey R Long

doi:10.1039/b615141h

Linkage isomerism in a face-centered cubic Cu6Cr8(CN)24 cluster with an S=15 ground state

Chem Commun (Camb). 2007 Apr 7:(13):1360-2. doi: 10.1039/b615141h. Epub 2007 Jan 19.

Authors

T David Harris¹, Jeffrey R Long

Affiliation

¹ Department of Chemistry, University of California, Berkeley, California 94720-1460, USA.

PMID: 17377682
DOI: 10.1039/b615141h

Abstract

Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN)24]4+, both exhibiting an S=15 ground state.