Abstract
Redox regulation of cell cycle progression during nitric oxide (NO) mediated cytostasis is not well-understood. In this study, we investigated the role of the intracellular antioxidant glutathione (GSH) in regulating specific signaling events that are associated with NO-mediated cell cycle arrest. Manipulation of intracellular GSH content through pharmacological inhibition of glutamate-cysteine ligase (GCL) indicated that GSH depletion potentiated nitrosative stress, DNA damage, phosphorylation of the tumor suppressor p53 (Ser-18) and upregulation of p21(cip1/waf1) upon NO stimulation. However, we found that neither overexpression of a dominant negative p53 nor pharmacological inhibition of p53 with cyclic pifithrin-alpha (cPFT-alpha) was sufficient to reverse NO-mediated cell cycle arrest or hypophosphorylation of retinoblastoma protein (Rb). We found that the decrease in cyclin D1 levels induced by NO was GSH-sensitive implying that the redox regulation of NO-mediated cytostasis was a multifaceted process and that both p53/p21(cip1/waf1) and p53 independent cyclin D1 pathways were involved. Together, our results demonstrate that GSH serves as an important component of cellular protective mechanisms against NO-derived nitrosative stress to regulate DNA damage checkpoint.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Animals
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Benzothiazoles / pharmacology
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Buthionine Sulfoximine / pharmacology
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Cell Cycle Proteins / antagonists & inhibitors
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Cell Cycle Proteins / genetics
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Cell Cycle Proteins / metabolism*
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Cell Proliferation / drug effects*
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Cyclin D
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Cyclin-Dependent Kinase Inhibitor p21 / metabolism
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Cyclins / metabolism
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DNA Damage
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Dose-Response Relationship, Drug
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Enzyme Inhibitors / pharmacology
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Fibroblasts / drug effects*
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Fibroblasts / enzymology
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Fibroblasts / metabolism
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G1 Phase / drug effects
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Glutamate-Cysteine Ligase / antagonists & inhibitors
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Glutamate-Cysteine Ligase / metabolism
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Glutathione / metabolism*
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Mice
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NIH 3T3 Cells
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Nitric Oxide / metabolism*
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Nitric Oxide Donors / pharmacology*
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Oxidation-Reduction
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Phosphorylation
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Retinoblastoma Protein / metabolism
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S Phase / drug effects
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Toluene / analogs & derivatives
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Toluene / pharmacology
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Transfection
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Triazenes / pharmacology*
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Tumor Suppressor Protein p53 / antagonists & inhibitors
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Tumor Suppressor Protein p53 / genetics
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Tumor Suppressor Protein p53 / metabolism
Substances
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1-hydroxy-2-oxo-3,3-bis(2-aminoethyl)-1-triazene
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Benzothiazoles
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Cdkn1a protein, mouse
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Cell Cycle Proteins
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Cyclin D
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Cyclin-Dependent Kinase Inhibitor p21
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Cyclins
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Enzyme Inhibitors
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Nitric Oxide Donors
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Retinoblastoma Protein
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Triazenes
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Tumor Suppressor Protein p53
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Nitric Oxide
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Toluene
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Buthionine Sulfoximine
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pifithrin
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Glutamate-Cysteine Ligase
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Glutathione