Oligosaccharide recognition and binding to the carbohydrate binding module of AMP-activated protein kinase

FEBS Lett. 2007 Oct 30;581(26):5055-9. doi: 10.1016/j.febslet.2007.09.044. Epub 2007 Sep 29.

Abstract

The AMP-activated protein kinase (AMPK) contains a carbohydrate-binding module (beta1-CBM) that is conserved from yeast to mammals. Beta1-CBM has been shown to localize AMPK to glycogen in intact cells and in vitro. Here we use Nuclear Magnetic Resonance spectroscopy to investigate oligosaccharide binding to 15N labelled beta1-CBM. We find that beta1-CBM shows greatest affinity to carbohydrates of greater than five glucose units joined via alpha,1-->4 glycosidic linkages with a single, but not multiple, glucose units in an alpha,1-->6 branch. The near identical chemical shift profile for all oligosaccharides whether cyclic or linear suggest a similar binding conformation and confirms the presence of a single carbohydrate-binding site.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • AMP-Activated Protein Kinases
  • Animals
  • Binding Sites
  • Multienzyme Complexes / chemistry*
  • Nuclear Magnetic Resonance, Biomolecular
  • Oligosaccharides / chemistry*
  • Protein Conformation
  • Protein Serine-Threonine Kinases / chemistry*
  • Receptors, Cell Surface / chemistry*

Substances

  • Multienzyme Complexes
  • Oligosaccharides
  • Receptors, Cell Surface
  • saccharide-binding proteins
  • Protein Serine-Threonine Kinases
  • AMP-Activated Protein Kinases