Preparation of an eight-membered sesquiterpene lactone resulting from sequential Gif System GoAgg(III) and MCPBA oxidation of (+)-10beta,14-dihydroxy-allo-aromadendrane

Márcia M L de Bodas; Maria Rita Marques; Adilson Beatriz; Dênis P de Lima

doi:10.3390/10081010

Preparation of an eight-membered sesquiterpene lactone resulting from sequential Gif System GoAgg(III) and MCPBA oxidation of (+)-10beta,14-dihydroxy-allo-aromadendrane

Molecules. 2005 Aug 31;10(8):1010-4. doi: 10.3390/10081010.

Authors

Márcia M L de Bodas¹, Maria Rita Marques, Adilson Beatriz, Dênis P de Lima

Affiliation

¹ Universidade Federal de Mato Grosso do Sul, Departamento de Química / CCET - CP 549 - 79070-900 - Campo Grande (MS) - Brazil.

Abstract

Studies aimed at a comparison of chemical, biomimetic (Gif system GoAgg(III))and enzymatic (CHMO) transformations of natural (+)-10beta,14-dihydroxy-allo-aromadendrane have led to preparation of an eight-member sesquiterpene lactone.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Biomimetic Materials / chemistry*
Chlorobenzoates / chemistry*
Isomerism
Lactones / chemical synthesis*
Lactones / chemistry
Oxidation-Reduction
Oxygenases / metabolism
Sesquiterpenes / chemistry*
Sesquiterpenes, Guaiane

Substances

10,14-dihydroxyaromadendrane
Chlorobenzoates
Lactones
Sesquiterpenes
Sesquiterpenes, Guaiane
aromadendrane
Oxygenases
cyclohexanone oxygenase
3-chloroperbenzoic acid