Abstract
Mononuclear manganese(II) and iron(III) flavonolates were synthesized as synthetic enzyme-substrate complexes, and their oxygenation reactions as biomimetic functional models with relevance to flavonol 2,4-dioxygenases are briefly described.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Crystallography, X-Ray
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Dioxygenases / chemistry*
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Flavonoids / chemistry*
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Iron / chemistry*
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Kinetics
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Manganese / chemistry*
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Models, Biological
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Models, Molecular
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Molecular Mimicry
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Molecular Structure
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Organometallic Compounds / chemical synthesis*
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Organometallic Compounds / chemistry
Substances
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Flavonoids
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Organometallic Compounds
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Manganese
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Iron
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Dioxygenases
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flavonol 2,4-dioxygenase