Mg 2+-doped GaN nanoparticles as blue-light emitters: a method to avoid sintering at high temperatures

Small. 2008 Jan;4(1):105-10. doi: 10.1002/smll.200700107.

Abstract

Bright blue-light emission at 410 nm is observed from Mg(2+)-doped GaN nanoparticles prepared by the nitridation of Ga(2)MgO(4) nanoparticles at 950 degrees C. The sintering of these nanoparticles during high-temperature nitridation was prevented by mixing the Ga(2)MgO(4) precursor nanoparticles with La(2)O(3) as an inert matrix before the nitridation process. The Mg(2+)-doped GaN nanoparticles were isolated from the matrix by etching with 10 % nitric acid. The Mg(2+)-doped GaN nanoparticles were characterized by photoluminescence, atomic force microscopy, X-ray diffraction, and IR analyses.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cations, Divalent / chemistry
  • Color
  • Gallium / chemistry*
  • Light*
  • Magnesium / chemistry*
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure
  • Microscopy, Atomic Force
  • Spectroscopy, Fourier Transform Infrared
  • Temperature*
  • X-Ray Diffraction

Substances

  • Cations, Divalent
  • gallium nitride
  • Gallium
  • Magnesium