Synthesis of (+)-zerumin B using a regioselective singlet oxygen furan oxidation

J Org Chem. 2008 Mar 7;73(5):2021-3. doi: 10.1021/jo7025405. Epub 2008 Feb 2.

Abstract

A short and efficient synthesis of the antitumor diterpenoid (+)-zerumin B has been accomplished starting from (+)-sclareolide. At the heart of the synthetic strategy lies the regioselective formation of the alpha-substituted gamma-hydroxybutenolide moiety of zerumin B. This was achieved by means of a [1,4] O-->C triisopropylsilyl migration followed by singlet oxygen (1 O 2) oxidation of the resulting 2-triisopropylsilyl-3-(alpha-hydroxy)alkylfuran.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Diterpenes / chemical synthesis*
  • Furans / chemistry*
  • Lactones / chemical synthesis*
  • Magnetic Resonance Spectroscopy
  • Oxidation-Reduction
  • Singlet Oxygen / chemistry*
  • Spectrometry, Mass, Electrospray Ionization
  • Stereoisomerism

Substances

  • Diterpenes
  • Furans
  • Lactones
  • zerumin B
  • Singlet Oxygen
  • furan