1 Dipartimento di Scienze e Tecnologie Avanzate, Interdisciplinary Center Nano-Sistemi, Università del Piemonte Orientale V, Bellini 25G, 15100 Alessandria, Italy.
A facile synthetic pathway leading to significant yields of bifunctional polyhedral oligomeric silsesquioxanes (POSS) with two different functionalities on the same cage structure, namely Ti-NH2POSS, is proposed in this manuscript.