Crowded, cell-like environment induces shape changes in aspherical protein

Proc Natl Acad Sci U S A. 2008 Aug 19;105(33):11754-9. doi: 10.1073/pnas.0803672105. Epub 2008 Aug 12.

Abstract

How the crowded environment inside cells affects the structures of proteins with aspherical shapes is a vital question because many proteins and protein-protein complexes in vivo adopt anisotropic shapes. Here we address this question by combining computational and experimental studies of a football-shaped protein (i.e., Borrelia burgdorferi VlsE) in crowded, cell-like conditions. The results show that macromolecular crowding affects protein-folding dynamics as well as overall protein shape. In crowded milieus, distinct conformational changes in VlsE are accompanied by secondary structure alterations that lead to exposure of a hidden antigenic region. Our work demonstrates the malleability of "native" proteins and implies that crowding-induced shape changes may be important for protein function and malfunction in vivo.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antigens, Bacterial / chemistry*
  • Antigens, Bacterial / metabolism*
  • Bacterial Proteins / chemistry*
  • Bacterial Proteins / metabolism*
  • Borrelia burgdorferi / chemistry
  • Borrelia burgdorferi / metabolism
  • Circular Dichroism
  • Computer Simulation
  • Lipoproteins / chemistry*
  • Lipoproteins / metabolism*
  • Models, Molecular
  • Protein Denaturation
  • Protein Folding*
  • Protein Structure, Secondary
  • Protein Structure, Tertiary
  • Thermodynamics

Substances

  • Antigens, Bacterial
  • Bacterial Proteins
  • Lipoproteins
  • VlsE protein, Borrelia burgdorferi