Abstract
A high yielding, batch mode synthesis of diaryl ethers and sulfides by an S(N)Ar fluoride-mediated process in scCO(2) has been developed; the use of a polymer-supported imidazolium fluoride reagent in batch mode led to the development of a fixed-bed continuous flow process, with high conversions.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Carbon Dioxide / chemistry*
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Chromatography, High Pressure Liquid / methods
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Chromatography, Supercritical Fluid
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Ethers / chemical synthesis*
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Ethers / chemistry
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Fluorobenzenes / chemistry
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Molecular Structure
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Pressure
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Sulfides / chemical synthesis
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Sulfides / chemistry
Substances
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Ethers
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Fluorobenzenes
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Sulfides
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Carbon Dioxide