FT-Raman spectrometry determination of Malathion in pesticide formulations

Guillermo Quintás; Salvador Garrigues; Miguel de la Guardia

doi:10.1016/j.talanta.2003.11.004

FT-Raman spectrometry determination of Malathion in pesticide formulations

Talanta. 2004 May 28;63(2):345-50. doi: 10.1016/j.talanta.2003.11.004.

Authors

Guillermo Quintás¹, Salvador Garrigues, Miguel de la Guardia

Affiliation

¹ Department of Analytical Chemistry, University of Valencia, Edifici Jeroni Muñoz, 50th Dr. Moliner, E46100 Burjassot, Valencia, Spain.

PMID: 18969438
DOI: 10.1016/j.talanta.2003.11.004

Abstract

A fast and environmentally friendly method has been developed for Fourier transform-Raman (FT-Raman) spectrometry determination of Malathion in pesticide emulsifiable concentrate formulations. The method is based on the measurement of intensity peak height values at 1737cm(-1) Raman shift corrected using a baseline defined at 1900cm(-1). Samples were diluted with CHCl(3) and the FT-Raman spectra collected in back-scattering mode over 3.3min at a nominal resolution of 4cm(-1) accumulating 50 scans per spectra and using a laser power of 1250mW. The developed procedure provided a limit of detection of 1.8% w/w in the original sample. Results found by FT-Raman spectrometry were statistically comparable with those obtained by flow injection Fourier transform infrared spectrometry, FIA-FTIR, and gas chromatography (GC) and were in good agreement with those reported by the manufacturer. The FT-Raman developed procedure reduces drastically the chlorinated solvent waste generation and avoids the contact of the operator with toxic products, being a fast alternative to the CIPAC recommended GC procedure.