Abstract
The concise enantioselective synthesis of hermitamides A and B is presented utilising a rhodium catalysed conjugate addition reaction to introduce the side chain and chiral information in a single step via an alkenyltrifluoroborate salt.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amides / chemical synthesis*
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Amides / chemistry
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Borates / chemistry*
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Catalysis
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Fluorine / chemistry*
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Hydrolysis
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Indoles / chemical synthesis*
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Indoles / chemistry
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Kinetics
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Phenethylamines / chemical synthesis*
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Phenethylamines / chemistry
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Rhodium / chemistry*
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Stereoisomerism
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Substrate Specificity
Substances
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Amides
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Borates
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Indoles
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Phenethylamines
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hermitamide A
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hermitamide B
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Fluorine
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Rhodium