Abstract
The copper-catalyzed insertions of nitriles into the Si-C bonds of silacyclopropenes provide azasilacyclopentadienes, which can be converted to allylic amines after reduction and protodesilylation. The enamine functionality of azasilacyclopentadienes also participates in 1,4-addition reactions and undergoes a hydroboration and oxidation sequence to form an allylic 1,2-amino alcohol.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Amines / chemistry
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Amino Alcohols / chemistry
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Aza Compounds / chemistry*
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Boric Acids / chemistry
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Carbon / chemistry
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Catalysis
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Copper / chemistry
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Cyclopentanes / chemistry*
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Nitriles / chemistry*
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Silicon / chemistry*
Substances
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Amines
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Amino Alcohols
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Aza Compounds
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Boric Acids
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Cyclopentanes
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Nitriles
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Carbon
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Copper
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boric acid
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Silicon