Synthesis of N,N'-dimethyl-N,N'-dibutyl malonamide functionalized polymer and its sorption affinities towards U(VI) and Th(IV) ions

S A Ansari; P K Mohapatra; V K Manchanda

doi:10.1016/j.talanta.2007.05.007

Synthesis of N,N'-dimethyl-N,N'-dibutyl malonamide functionalized polymer and its sorption affinities towards U(VI) and Th(IV) ions

Talanta. 2007 Oct 31;73(5):878-85. doi: 10.1016/j.talanta.2007.05.007. Epub 2007 May 18.

Authors

S A Ansari¹, P K Mohapatra, V K Manchanda

Affiliation

¹ Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India.

PMID: 19073115
DOI: 10.1016/j.talanta.2007.05.007

Abstract

A novel chelating polymeric material was synthesized by chemical anchoring of N,N'-dimethyl-N,N'-dibutyl malonamide (DMDBMA) with chloromethylated polystyrene-divinyl benzene polymer. The polymeric material thus prepared was characterized by (13)C NMR, FT-IR spectroscopy and CHN elemental analysis. The fabricated polymeric material exhibited superior binding for hexa-valent and tetra-valent metal ions such as U(VI) and Th(IV). Various physico-chemical properties of the functionalized polymer like phase adsorption kinetics, metal sorption mechanism and metal sorption capacity was studied in the static method. Adsorption kinetics studies show that <20min was sufficient for >99.99% adsorption of Th(IV) and U(VI). The kinetics for adsorption of U(VI) and Th(IV) was found to follow the first order Lagergren rate kinetics. Adsorption of U(VI) on the malonamide functionalized polymer followed the Langmuir adsorption isotherm. The Langmuir monolayer adsorption phenomenon was also confirmed by the theoretical approach calculated based on the adsorption kinetics. The metal sorption capacities for uranium and thorium were found to be 18.78+/-1.53mg and 15.74+/-1.59mg/g of the chelating polymer at 3M HNO(3), respectively.