PET imaging of HSV1-tk mutants with acquired specificity toward pyrimidine- and acycloguanosine-based radiotracers

Eur J Nucl Med Mol Imaging. 2009 Aug;36(8):1273-82. doi: 10.1007/s00259-009-1089-x. Epub 2009 Mar 4.

Abstract

Purpose: The aim of this study was to create an alternative mutant of the herpes simplex virus type 1 thymidine kinase (HSV1-tk) reporter gene with reduced phosphorylation capacity for acycloguanosine derivatives, but not pyrimidine-based compounds that will allow for successful PET imaging.

Methods: A new mutant of HSV1-tk reporter gene, suitable for PET imaging using pyrimidine-based radiotracers, was developed. The HSV1-tk mutant contains an arginine-to-glutamine substitution at position 176 (HSV1-R176Qtk) of the nucleoside binding region of the enzyme.

Results: The mutant-gene product showed favorable enzymatic characteristics toward pyrimidine-based nucleosides, while exhibiting reduced activity with acycloguanosine derivatives. In order to enhance HSV1-R176Qtk reporter activity with pyrimidine-based radiotracers, we introduced the R176Q substitution into the more active HSV1-sr39tk mutant. U87 human glioma cells transduced with the HSV1-R176Qsr39tk double mutant reporter gene showed high (3)H-FEAU pyrimidine nucleoside and low (3)H-penciclovir acycloguanosine analog uptake in vitro. PET imaging also demonstrated high (18)F-FEAU and low (18)F-FHBG accumulation in HSV1-R176Qsr39tk+ xenografts. The feasibility of imaging two independent nucleoside-specific HSV1-tk mutants in the same animal with PET was demonstrated. Two opposite xenografts expressing the HSV1-R176Qsr39tk reporter gene and the previously described acycloguanosine-specific mutant of HSV1-tk, HSV1-A167Ysr39tk reporter gene, were imaged using a short-lived pyrimidine-based (18)F-FEAU and an acycloguanosine-based (18)F-FHBG radiotracer, respectively, administered on 2 consecutive days.

Conclusion: We conclude that in combination with acycloguanosine-specific HSV1-A167Ysr39tk reporter gene, a HSV1-tk mutant containing the R176Q substitution could be used for PET imaging of two different cell populations or concurrent molecular biological processes in the same living subject.

MeSH terms

  • Acyclovir / administration & dosage
  • Acyclovir / chemistry
  • Acyclovir / metabolism*
  • Acyclovir / pharmacology
  • Amino Acid Substitution
  • Animals
  • Cell Line, Tumor
  • Drug Resistance, Viral
  • Gene Expression Regulation, Neoplastic
  • Genes, Reporter
  • Herpesvirus 1, Human / enzymology*
  • Herpesvirus 1, Human / physiology
  • Humans
  • Mice
  • Mutation*
  • Neoplasms / diagnostic imaging
  • Neoplasms / genetics
  • Neoplasms / metabolism
  • Phosphorylation
  • Positron-Emission Tomography*
  • Pyrimidines / administration & dosage
  • Pyrimidines / chemistry
  • Pyrimidines / metabolism*
  • Radioactive Tracers
  • Substrate Specificity
  • Thymidine Kinase / genetics*
  • Thymidine Kinase / metabolism*

Substances

  • Pyrimidines
  • Radioactive Tracers
  • Thymidine Kinase
  • pyrimidine
  • Acyclovir