cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe III and Pd II coordination clusters

Dalton Trans. 2009 Mar 7:(9):1549-53. doi: 10.1039/b815200d. Epub 2009 Jan 26.

Abstract

A dodecanuclear Fe(III) complex, consisting of two {Fe(6)} units coupled across a single hydroxy-bridge and a cage-like Pd(II) trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N',N',N'',N''-hexaacetic acid (H(6)hact).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Ferric Compounds / chemistry*
  • Ligands
  • Organometallic Compounds / chemical synthesis*
  • Organometallic Compounds / chemistry
  • Palladium / chemistry*

Substances

  • Ferric Compounds
  • Ligands
  • Organometallic Compounds
  • Palladium