Avid interactions underlie the Lys63-linked polyubiquitin binding specificities observed for UBA domains

Nat Struct Mol Biol. 2009 Aug;16(8):883-9. doi: 10.1038/nsmb.1637. Epub 2009 Jul 20.

Abstract

Ubiquitin (denoted Ub) receptor proteins as a group must contain a diverse set of binding specificities to distinguish the many forms of polyubiquitin (polyUb) signals. Previous studies suggested that the large class of ubiquitin-associated (UBA) domains contains members with intrinsic specificity for Lys63-linked polyUb or Lys48-linked polyUb, thus explaining how UBA-containing proteins can mediate diverse signaling events. Here we show that previously observed Lys63-polyUb selectivity in UBA domains is the result of an artifact in which the dimeric fusion partner, glutathione S-transferase (GST), positions two UBAs for higher affinity, avid interactions with Lys63-polyUb, but not with Lys48-polyUb. Freed from GST, these UBAs are either nonselective or prefer Lys48-polyUb. Accordingly, NMR experiments reveal no Lys63-polyUb-specific binding epitopes for these UBAs. We reexamine previous conclusions based on GST-UBAs and present an alternative model for how UBAs achieve a diverse range of linkage specificities.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Binding Sites
  • Binding, Competitive
  • Electrophoresis, Polyacrylamide Gel
  • Fluorescence Polarization
  • Glutathione Transferase / chemistry
  • Glutathione Transferase / genetics
  • Glutathione Transferase / metabolism
  • Kinetics
  • Lysine / chemistry
  • Lysine / metabolism
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Polyubiquitin / chemistry
  • Polyubiquitin / metabolism*
  • Protein Binding
  • Protein Multimerization
  • Protein Structure, Tertiary*
  • Saccharomyces cerevisiae Proteins / chemistry
  • Saccharomyces cerevisiae Proteins / genetics
  • Saccharomyces cerevisiae Proteins / metabolism*
  • Surface Plasmon Resonance
  • Ubiquitin / chemistry
  • Ubiquitin / metabolism*

Substances

  • Ede1 protein, S cerevisiae
  • Saccharomyces cerevisiae Proteins
  • Ubiquitin
  • Polyubiquitin
  • Glutathione Transferase
  • Lysine