High-yielding synthesis of sphingoid-type bases

J Org Chem. 2009 Sep 18;74(18):6986-92. doi: 10.1021/jo901567q.

Abstract

An efficient methodology for the synthesis of sphingoid-type bases is reported. It involves the stereoselective addition of a racemic 3-alkoxy allenylzinc to enantiopure N-tert-butylsulfinyl imines and a cross-metathesis reaction as the key steps. It has been successfully applied to the syntheses of sphinganine and naturally occurring bioactive related compounds, among which the hydrolysis product of clavaminol H and two spisulosines. All of these compounds have been prepared in six steps from N-tert-butylsulfinyl imines in high overall yields (>56%).

MeSH terms

  • Alcohols / chemistry
  • Alkenes / chemistry
  • Amino Alcohols / chemistry
  • Antineoplastic Agents / chemical synthesis
  • Imines / chemistry
  • Models, Chemical
  • Organometallic Compounds / chemistry
  • Sphingosine / analogs & derivatives*
  • Sphingosine / chemical synthesis
  • Stereoisomerism
  • Sulfonium Compounds / chemistry
  • Zinc / chemistry

Substances

  • Alcohols
  • Alkenes
  • Amino Alcohols
  • Antineoplastic Agents
  • Imines
  • Organometallic Compounds
  • Sulfonium Compounds
  • alkoxyl radical
  • sulfinimine
  • Zinc
  • Sphingosine
  • safingol