Synthesis of N-succinyl-L,L-diaminopimelic acid mimetics via selective protection

Protein Pept Lett. 2010 Mar;17(3):405-9. doi: 10.2174/092986610790780387.

Abstract

The search for potential inhibitors that target so far unexplored bacterial enzyme mono-N-succinyl-L,L-diaminopimelic acid desuccinylase (DapE) has stimulated a development of methodology for quick and efficient preparation of mono-N-acylated 2,6-diaminopimelic acid (DAP) derivatives bearing the different carboxyl groups or lipophilic moieties on their amino group.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acylation
  • Biomimetic Materials / chemical synthesis*
  • Biomimetic Materials / chemistry
  • Chromatography, High Pressure Liquid
  • Diaminopimelic Acid / analogs & derivatives*
  • Diaminopimelic Acid / chemical synthesis*
  • Diaminopimelic Acid / chemistry
  • Metabolic Networks and Pathways
  • Models, Molecular
  • Spectrometry, Mass, Electrospray Ionization
  • Succinates / chemical synthesis*
  • Succinates / chemistry
  • Succinyldiaminopimelate Transaminase / antagonists & inhibitors
  • Succinyldiaminopimelate Transaminase / metabolism

Substances

  • Succinates
  • Diaminopimelic Acid
  • Succinyldiaminopimelate Transaminase