Abstract
Thiosilane and a catalytic amount of a Brønsted acid mediate the novel domino-type rearrangement reaction of the 4,4-disubstituted cyclohexadienones to produce the 3,4-disubstituted benzenethioethers; the key step is 1,2-addition of thiosilane to dienone.
MeSH terms
-
Acids / chemistry
-
Catalysis
-
Cyclohexenes / chemistry*
-
Ketones / chemistry
-
Molecular Structure
-
Silanes / chemistry*
-
Sulfhydryl Compounds / chemical synthesis
-
Sulfhydryl Compounds / chemistry
Substances
-
Acids
-
Cyclohexenes
-
Ketones
-
Silanes
-
Sulfhydryl Compounds
-
cyclohexadienone