Abstract
Isolated and patterned assemblies of Ir(4)-based metal polyhedra are described, in which a coordinated calixarene phosphine ligand enforces the desired cluster organization. The compounds are characterized by single-crystal X-ray diffraction and infrared spectroscopy.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Calixarenes / chemistry*
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Crystallography, X-Ray
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Iridium / chemistry*
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Ligands
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Models, Molecular
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Spectrophotometry, Infrared
Substances
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Ligands
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Organometallic Compounds
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Calixarenes
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Iridium