The solution structure of (+)-spongistatin 1 in DMSO

Org Lett. 2010 Apr 16;12(8):1788-91. doi: 10.1021/ol100417d.

Abstract

The solution structure of (+)-spongistatin 1 (1) has been determined via 1- and 2-D NMR techniques in conjunction with extensive in silico conformational analysis to comprise a mixture of 4 major rapidly interconverting conformational families.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Dimethyl Sulfoxide / chemistry*
  • Macrolides / chemistry*
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Molecular Conformation
  • Solutions
  • Stereoisomerism

Substances

  • Macrolides
  • Solutions
  • spongistatin 1
  • Dimethyl Sulfoxide