Abstract
A new approach for one step olefination of benzaldehydes into hydroxy functionalized OPVs is achieved through the first domino Knoevenagel-decarboxylation-Heck sequence using a single catalyst system. The methodology also led to new oxygen based OPV scaffolds capable of selective and visible fluoride recognition in organic or aqueous medium.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Benzaldehydes / chemistry*
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Catalysis
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Decarboxylation
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Fluorides / chemistry*
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Molecular Structure
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Organometallic Compounds / chemistry*
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Palladium / chemistry*
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Polyvinyls / chemical synthesis*
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Polyvinyls / chemistry
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Stereoisomerism
Substances
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Alkenes
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Benzaldehydes
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Organometallic Compounds
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Polyvinyls
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oligo(p-phenylene vinylene)
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Palladium
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Fluorides