A metal-organic framework with a covalently prefabricated porous organic linker

Shashikala I Swamy; John Bacsa; James T A Jones; Kyriakos C Stylianou; Alexander Steiner; Lyndsey K Ritchie; Tom Hasell; Jamie A Gould; Andrea Laybourn; Yaroslav Z Khimyak; Dave J Adams; Matthew J Rosseinsky; Andrew I Cooper

doi:10.1021/ja104083y

A metal-organic framework with a covalently prefabricated porous organic linker

J Am Chem Soc. 2010 Sep 22;132(37):12773-5. doi: 10.1021/ja104083y.

Authors

Shashikala I Swamy¹, John Bacsa, James T A Jones, Kyriakos C Stylianou, Alexander Steiner, Lyndsey K Ritchie, Tom Hasell, Jamie A Gould, Andrea Laybourn, Yaroslav Z Khimyak, Dave J Adams, Matthew J Rosseinsky, Andrew I Cooper

Affiliation

¹ Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool L69 7ZD, United Kingdom.

PMID: 20795723
DOI: 10.1021/ja104083y

Abstract

We report here the synthesis of a metal-organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.