Abstract
β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Flavins / chemistry*
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Hydrogen Peroxide / chemistry*
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Oxidation-Reduction
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Stereoisomerism
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Sulfides / chemistry*
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Water / chemistry
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beta-Cyclodextrins / chemistry*
Substances
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Flavins
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Sulfides
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beta-Cyclodextrins
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Water
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methylphenylsulfide
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Hydrogen Peroxide
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betadex