Abstract
Four 5-carbon-linked trioxane dimer orthoesters (6a-6d) have been prepared in 4 or 5 chemical steps from the natural trioxane artemisinin (1). When administered orally to malaria-infected mice using a single dose of only 6 mg/kg body weight along with 18 mg/kg of mefloquine hydrochloride, trioxane dimer orthoester sulfone 6d completely and safely cured the mice; after 30 days, the cured mice showed no detectable parasitemia, gained at least as much weight as the control mice (no infection), and behaved normally.
Copyright © 2010 Elsevier Ltd. All rights reserved.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Administration, Oral
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Animals
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Antimalarials / administration & dosage
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Antimalarials / therapeutic use*
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Artemisinins / therapeutic use
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Crystallography, X-Ray
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Drug Therapy, Combination
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Esters / chemistry
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Esters / therapeutic use*
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Heterocyclic Compounds / therapeutic use*
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Heterocyclic Compounds, 4 or More Rings / chemistry
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Heterocyclic Compounds, 4 or More Rings / therapeutic use*
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Malaria / drug therapy
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Mefloquine / therapeutic use*
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Mice
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Molecular Structure
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Plasmodium berghei / drug effects*
Substances
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1,2,4-trioxane
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Antimalarials
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Artemisinins
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Esters
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Heterocyclic Compounds
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Heterocyclic Compounds, 4 or More Rings
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artemisinin
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Mefloquine