Separation of fast from slow anabolism by site-specific PEGylation of insulin-like growth factor I (IGF-I)

J Biol Chem. 2011 Jun 3;286(22):19501-10. doi: 10.1074/jbc.M110.172189. Epub 2011 Apr 1.

Abstract

Insulin-like growth factor I (IGF-I) has important anabolic and homeostatic functions in tissues like skeletal muscle, and a decline in circulating levels is linked with catabolic conditions. Whereas IGF-I therapies for musculoskeletal disorders have been postulated, dosing issues and disruptions of the homeostasis have so far precluded clinical application. We have developed a novel IGF-I variant by site-specific addition of polyethylene glycol (PEG) to lysine 68 (PEG-IGF-I). In vitro, this modification decreased the affinity for the IGF-I and insulin receptors, presumably through decreased association rates, and slowed down the association to IGF-I-binding proteins, selectively limiting fast but maintaining sustained anabolic activity. Desirable in vivo effects of PEG-IGF-I included increased half-life and recruitment of IGF-binding proteins, thereby reducing risk of hypoglycemia. PEG-IGF-I was equipotent to IGF-I in ameliorating contraction-induced muscle injury in vivo without affecting muscle metabolism as IGF-I did. The data provide an important step in understanding the differences of IGF-I and insulin receptor contribution to the in vivo activity of IGF-I. In addition, PEG-IGF-I presents an innovative concept for IGF-I therapy in diseases with indicated muscle dysfunction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cell Line
  • Dogs
  • Half-Life
  • Humans
  • Hypoglycemia / chemically induced
  • Hypoglycemia / metabolism
  • Insulin-Like Growth Factor Binding Proteins / metabolism
  • Insulin-Like Growth Factor I / chemistry
  • Insulin-Like Growth Factor I / pharmacokinetics*
  • Insulin-Like Growth Factor I / pharmacology
  • Muscle, Skeletal / metabolism*
  • Muscle, Skeletal / pathology
  • Musculoskeletal Diseases / drug therapy*
  • Musculoskeletal Diseases / metabolism
  • Musculoskeletal Diseases / pathology
  • Polyethylene Glycols / chemistry
  • Polyethylene Glycols / pharmacokinetics*
  • Polyethylene Glycols / pharmacology
  • Receptor, Insulin / agonists*
  • Receptor, Insulin / metabolism

Substances

  • Insulin-Like Growth Factor Binding Proteins
  • Polyethylene Glycols
  • Insulin-Like Growth Factor I
  • Receptor, Insulin