Inhibition of erythrocyte Ca2(+)-pump by Ca2+ antagonists

Biochem Pharmacol. 1990 Dec 1;40(11):2549-55. doi: 10.1016/0006-2952(90)90098-6.

Abstract

Inside-out vesicularized membrane fragments from human erythrocytes were prepared to study the effects of various Ca2+ channel entry blockers of plasma membrane Ca2+ transport and (Ca2+ + Mg2+)-ATPase activity concomitantly. Verapamil and diltiazem (0.01 to 5 mM) inhibited both (Ca2+ + Mg2+)-ATPase activity and initial rates of 45Ca2+ net uptake analogously. In general, the parameter affected most by these drugs, using either Ca2+ transport or (Ca2+ + Mg2+)-5'-adenosine-triphospho-hydrolase (EC 3.6.1.3) ([Ca2+ + Mg2+]-ATPase) measurements, was the stimulation by calmodulin. However, the specificity and selectivity of inhibition appeared to be highly concentration and membrane preparation dependent. Verapamil and diltiazem inhibited the calmodulin-Ca2+ transport concentration-effect relationship by changing its apparent affinity as well as the maximal velocity of the process. In a "white ghost" membrane preparation, bepridil inhibited calmodulin activation with a high degree of selectivity as opposed to its effects on calmodulin activation in the vesicular preparation. Nifedipine failed to exhibit any specificity and modestly inhibited basal and calmodulin-activated inside-out vesicular Ca2+ transport and (Ca2+ + Mg2+)-ATPase alike. Our results suggest that verapamil, diltiazem and bepridil (0.01 to 0.3 mM), but not nifedipine (1 nM to 0.01 mM), in relatively high concentrations can antagonize the calmodulin-stimulated Ca2(+)-pump, i.e. the ATPase as well as the transport process. The inhibitors differed with regard to potency, selectivity, and the type of inhibition they produced.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biological Transport, Active / drug effects
  • Ca(2+) Mg(2+)-ATPase / antagonists & inhibitors
  • Calcium / metabolism*
  • Calcium Channel Blockers / pharmacology*
  • Calcium-Transporting ATPases / antagonists & inhibitors
  • Diltiazem / pharmacology
  • Erythrocytes / metabolism*
  • Humans
  • Verapamil / pharmacology

Substances

  • Calcium Channel Blockers
  • Verapamil
  • Ca(2+) Mg(2+)-ATPase
  • Calcium-Transporting ATPases
  • Diltiazem
  • Calcium