A linear single-molecule magnet based on [Ru(III)(CN)6]3-

Kasper S Pedersen; Jan Dreiser; Joscha Nehrkorn; Maren Gysler; Magnus Schau-Magnussen; Alexander Schnegg; Karsten Holldack; Robert Bittl; Stergios Piligkos; Høgni Weihe; Philip Tregenna-Piggott; Oliver Waldmann; Jesper Bendix

doi:10.1039/c1cc12158h

A linear single-molecule magnet based on [Ru(III)(CN)6]3-

Chem Commun (Camb). 2011 Jun 28;47(24):6918-20. doi: 10.1039/c1cc12158h. Epub 2011 May 20.

Authors

Kasper S Pedersen¹, Jan Dreiser, Joscha Nehrkorn, Maren Gysler, Magnus Schau-Magnussen, Alexander Schnegg, Karsten Holldack, Robert Bittl, Stergios Piligkos, Høgni Weihe, Philip Tregenna-Piggott, Oliver Waldmann, Jesper Bendix

Affiliation

¹ Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100, Copenhagen, Denmark. [email protected] [email protected]

PMID: 21603702
DOI: 10.1039/c1cc12158h

Abstract

We report the synthesis, structure and magnetic properties of the first molecular cluster and single-molecule magnet to incorporate [Ru(III)(CN)(6)](3-). Frequency-domain Fourier-transform THz-EPR (FDFT THz-EPR) and magnetic susceptibility measurements indicate strongly anisotropic Mn-Ru exchange interactions.