Enhanced sonochemical degradation of azure B dye by the electroFenton process

Ultrason Sonochem. 2012 Jan;19(1):174-8. doi: 10.1016/j.ultsonch.2011.05.013. Epub 2011 May 25.

Abstract

The degradation of azure B dye (C15H16ClN3S; AB) has been studied by Fenton, sonolysis and sono-electroFenton processes employing ultrasound at 23 kHz and the electrogeneration of H2O2 at the reticulated vitreous carbon electrode. It was found that the dye degradation followed apparent first-order kinetics in all the degradation processes tested. The rate constant was affected by both the pH of the solution and initial concentration of Fe2+, with the highest degradation obtained at pH between 2.6 and 3. The first-order rate constant decreased in the following order: sono-electroFenton>Fenton>sonolysis. The rate constant for AB degradation by sono-electroFenton is ∼10-fold that of sonolysis and ∼2-fold the one obtained by Fenton under silent conditions. The chemical oxygen demand was abated ∼68% and ∼85% by Fenton and sono-electroFenton respectively, achieving AB concentration removal over 90% with both processes.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Azure Stains / chemistry*
  • Carbon / chemistry
  • Electrochemistry
  • Electrodes
  • Ferrous Compounds / chemistry
  • Hydrogen-Ion Concentration
  • Kinetics
  • Molecular Structure
  • Ultrasonics*

Substances

  • Azure Stains
  • Ferrous Compounds
  • Carbon
  • Azure B