Testing the resistance of fullerenes to chemothermal oxidation used to isolate soots from environmental samples

We tested the resistance of five different fullerenes (C(60), C(70), C(76/78) mix, and C(84)) to chemothermal oxidation at 375 °C (CTO-375), a method that has been used and tested for quantifying black carbon (BC) and CNTs in soils and sediments. C(60) survived CTO-375 the most (50%), while C(70) was the fullerene with the lowest survival rate (<1%). Standard additions of C(60) to soil and sediment reference materials yielded recoveries between 18 and 36%. Although lower than recoveries previously observed for soot and CNTs, these results demonstrate the capability of CTO-375 to partially isolate C(60) from solid environmental matrices. Standard additions of C(70), C(76/78), and C(84) yielded slightly higher survival rates when added to soil and sediment than in their pure form. These results indicate that the mineral matrices of these samples probably had a catalytic effect towards C(60) and a protective effect towards C(70), C(76/78), and C(84) during CTO-375.