We construct a flexible pn heterostructured photodiode using a CdTe nanoparticle thin film and a single ZnO nanowire (NW) on a plastic substrate. The photocurrent characteristics of the flexible photodiode are examined under illumination with 325 nm wavelength light and the photocurrent efficiencies at bias voltages of ± 2.5 V are estimated to be 8.0 and 2.1 µA W(-1) under forward and reverse bias conditions, respectively. The photocurrent generation of the pn heterostructured photodiode is dominantly associated with the transport of the photogenerated charge carriers in the single ZnO NW. Furthermore, the operations of our flexible photodiode are investigated in the upwardly and downwardly bent states, as well as in the flat state.