Transmission gratings that combine a large diffraction angle with a high diffraction efficiency and a low angular and wavelength dispersion could be used to collect sunlight in a light guide. In this paper we compare the diffractive properties of polarization gratings and classical surface-relief gratings and explore their possible use in solar concentrators. It is found that polarization gratings and surface-relief gratings have qualitatively comparable diffraction characteristics when their thickness parameters are within the same regime. Relatively large grating periods result in high diffraction efficiencies over a wide range of incident angles. For small grating periods the efficiency and the angular acceptance are decreased. Surface-relief gratings are preferred over polarization gratings as in-couplers for solar concentrators.