Molecular imaging of Cathepsin E-positive tumors in mice using a novel protease-activatable fluorescent probe

Mol Biosyst. 2011 Dec;7(12):3207-3213. doi: 10.1039/c1mb05215b. Epub 2011 Sep 20.

Abstract

The purpose of this study is to demonstrate the ability of imaging Cathepsin E (Cath E) positive tumors in living animals through selective targeting of Cath E proteolytic activity using a sensitive molecular imaging agent.

Methods: A peptide-based Cath E imaging probe and a control probe were synthesized for this study. Human Cath E-positive cancer cells (MPanc96-E) were implanted subcutaneously in nude mice. Tumor-bearing mice were examined in vivo with near-infrared fluorescence (NIRF) imaging at various time points after intravenous injection of the Cath E sensing imaging probe. Excised organs and tissues of interest were further imaged ex vivo.

Results: Upon specific Cath E proteolytic activation, the NIRF signal of the imaging probe a was converted from an optically quenched initial state to a highly fluorescent active state. Imaging probe a was able to highlight the Cath E-positive tumors as early as 24 h post injection. Fluorescent signal in tumor was 3-fold higher than background. The confined specificity of imaging probe a to tumor associated Cath E was verified by using control imaging probe b. Both in vivo and ex vivo imaging results confirmed the superior selectivity and sensitivity of imaging probe a in Cath E imaging.

Conclusions: The small animal studies demonstrated the capability of probe a for imaging Cath E-positive tumors. The developed optical probe could be applied in early diagnostic imaging and guiding subsequent surgical procedure.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Biomarkers, Tumor / analysis
  • Cathepsin E / analysis*
  • Cell Line, Tumor
  • Diagnostic Imaging
  • Fluorescent Dyes
  • Humans
  • Mice
  • Mice, Nude
  • Molecular Imaging / methods*
  • Neoplasms / chemistry*
  • Neoplasms / diagnosis

Substances

  • Biomarkers, Tumor
  • Fluorescent Dyes
  • Cathepsin E