Abstract
The intermolecular C-H cross-coupling between aromatic ethers has been achieved for the first time using perfluorinated hypervalent iodine(III) compounds as extreme single-electron-transfer (SET) oxidants. The demonstrations of this specific coupling could provide a direct route to valuable oxygenated mixed naphthalene-benzene biaryls 3 only, without formation of other biaryl-derived byproducts.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemical synthesis*
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Benzene Derivatives / chemistry*
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Catalysis
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Combinatorial Chemistry Techniques
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Hydrocarbons, Fluorinated / chemistry*
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Hydrocarbons, Iodinated / chemistry*
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Metals
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Naphthalenes / chemical synthesis*
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Naphthalenes / chemistry*
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Oxidation-Reduction
Substances
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Benzene Derivatives
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Hydrocarbons, Fluorinated
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Hydrocarbons, Iodinated
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Metals
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Naphthalenes