Extracranial measurements of amide proton transfer using exchange-modulated point-resolved spectroscopy (EXPRESS)

NMR Biomed. 2012 Jun;25(6):829-34. doi: 10.1002/nbm.1798. Epub 2011 Dec 2.

Abstract

Chemical exchange saturation transfer (CEST) imaging has been used experimentally in a large range of applications. However, full quantification of CEST effects in vivo using standard imaging sequences is time consuming as a large number of saturation frequency offsets, each followed by an imaging readout, are required to define a z spectrum. Furthermore, outside the brain, the presence of fat can confound the interpretation of z spectra. A novel acquisition and post-processing technique is presented in this study, named exchange-modulated point-resolved spectroscopy (EXPRESS), which aims to address these limitations and to enable spatially localised, high signal-to-noise measurements of CEST effects in vivo. Using amide proton exchange (APT) measurements in tumours, it is demonstrated that the acquisition of two-dimensional EXPRESS spectra composed of chemical shift and saturation frequency offset dimensions allows the correction of CEST data containing both fat and water signals, which is a common confounding property of tissues found outside the brain.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amides / analysis*
  • Animals
  • Biomarkers, Tumor / analysis*
  • Cell Line, Tumor
  • Colorectal Neoplasms / chemistry*
  • Colorectal Neoplasms / diagnosis*
  • Lipids / analysis*
  • Mice
  • Mice, Nude
  • Protons
  • Reproducibility of Results
  • Sensitivity and Specificity
  • Spectrum Analysis / methods*

Substances

  • Amides
  • Biomarkers, Tumor
  • Lipids
  • Protons