A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

Verónica de la Fuente; Cyril Godard; Ennio Zangrando; Carmen Claver; Sergio Castillón

doi:10.1039/c2cc17124d

A phosphine-free Pd catalyst for the selective double carbonylation of aryl iodides

Chem Commun (Camb). 2012 Feb 4;48(11):1695-7. doi: 10.1039/c2cc17124d. Epub 2011 Dec 21.

Authors

Verónica de la Fuente¹, Cyril Godard, Ennio Zangrando, Carmen Claver, Sergio Castillón

Affiliation

¹ Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain.

PMID: 22190125
DOI: 10.1039/c2cc17124d

Abstract

The first phosphine-free Pd-catalysed double carbonylation of aryl iodides is reported as a general and practical method, giving excellent conversions and selectivities for a wide range of aryl iodides and amine nucleophiles under atmospheric CO pressure.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Carbon Monoxide / chemistry*
Catalysis
Iodides / chemistry*
Palladium / chemistry*
Urea / analogs & derivatives*
Urea / chemistry

Substances

Iodides
Palladium
Carbon Monoxide
Urea
N,N'-dibutylurea