A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite

Org Biomol Chem. 2012 Apr 14;10(14):2862-9. doi: 10.1039/c2ob06821d. Epub 2012 Mar 2.

Abstract

Carbonyl compounds react with organozinc reagents in the presence of diphenyl phosphite to give the corresponding olefins. A variety of 1,3-dienes and unsaturated esters were obtained in moderate to excellent yields under mild conditions.