Development of a universal colorimetric indicator for G-quadruplex structures by the fusion of thiazole orange and isaindigotone skeleton

Anal Chem. 2012 Aug 7;84(15):6288-92. doi: 10.1021/ac300207r. Epub 2012 Jul 20.

Abstract

The rapid and convenient method for identification of all kinds of G-quadruplex is highly desirable. In the present study, a novel colorimetric indicator for a vast variety of G-quadruplex was designed and synthesized on the basis of thiazole orange and isaindigotone skeleton. Its distinct color change enables label-free visual detection of G-quadruplexes, which is due to the disassembly of dye H-aggregates to monomers. This specific detection of G-quadruplex arises from its end-stacking interaction with G-quartet. On the basis of this universal indicator, a facile approach for large-scale identification of G-quadruplex was developed.

Publication types

  • Letter
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkaloids / chemistry*
  • Benzothiazoles / chemistry*
  • Colorimetry*
  • Fluorescence Resonance Energy Transfer
  • G-Quadruplexes*
  • Indicators and Reagents / chemistry
  • Quinazolines / chemistry*
  • Quinolines / chemistry*

Substances

  • Alkaloids
  • Benzothiazoles
  • Indicators and Reagents
  • Quinazolines
  • Quinolines
  • isaindigotone
  • thiazole orange