Synthesis of a Fe(II)SH complex stabilized by an intramolecular N-H···S hydrogen bond, which acts as a H2S donor

Erwan Galardon; Thomas Roger; Patrick Deschamps; Pascal Roussel; Alain Tomas; Isabelle Artaud

doi:10.1021/ic300952d

Synthesis of a Fe(II)SH complex stabilized by an intramolecular N-H···S hydrogen bond, which acts as a H2S donor

Inorg Chem. 2012 Oct 1;51(19):10068-70. doi: 10.1021/ic300952d. Epub 2012 Sep 7.

Authors

Erwan Galardon¹, Thomas Roger, Patrick Deschamps, Pascal Roussel, Alain Tomas, Isabelle Artaud

Affiliation

¹ Laboratoire de Chimie et Biochimie Pharmacologique et Toxicologique, UMR 8601 CNRS, Université Paris Descartes, PRES Paris cité, 45 rue des Saints Pères, 75270 Paris Cedex 06, France. [email protected]

PMID: 22957658
DOI: 10.1021/ic300952d

Abstract

Through use of the reversible protonation of an iron(II) complex containing a deprotonated carboxamido moiety, we prepared and fully characterized the first hydrogen(sulfido)iron(II) complex stabilized by an intramolecular hydrogen bond, which acts as a H(2)S donor in solution.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Coordination Complexes / chemical synthesis*
Coordination Complexes / chemistry
Ferrous Compounds / chemical synthesis*
Ferrous Compounds / chemistry
Hydrogen Bonding
Models, Molecular
Sulfhydryl Compounds / chemical synthesis*
Sulfhydryl Compounds / chemistry

Substances

Coordination Complexes
Ferrous Compounds
Sulfhydryl Compounds