Thioredoxin-1 functions as a molecular switch regulating the oxidative stress-induced activation of MST1

Free Radic Biol Med. 2012 Dec 15;53(12):2335-43. doi: 10.1016/j.freeradbiomed.2012.10.527. Epub 2012 Oct 17.

Abstract

The mammalian STE20-like kinase-1 (MST1), a multifunctional serine-threonine kinase in mammalian cells, has been recently implicated in the mediation of oxidative stress-induced signaling processes that lead to cell death. However, the molecular mechanism by which oxidative stress induces the stimulation of MST1 remains unclear. In this study, we found that thioredoxin-1 was physically associated with MST1 in intact cells and that this interaction was abolished by H2O2. Thioredoxin-1, by binding to the SARAH domain of MST1, inhibited the homodimerization and autophosphorylation of MST1, thereby preventing its activation. Furthermore, TNF-α prevented the physical interaction between thioredoxin-1 and MST1 and promoted the homodimerization and activation of MST1. The effect of TNF-α on MST1 activation was reversed by the reducing agent N-acetyl-l-cysteine. Taken together, our results suggest that thioredoxin-1 functions as a molecular switch to turn off the oxidative stress-induced activation of MST1.

Keywords: Free radicals; MST1; Reactive oxygen species; TNF-α; Thioredoxin-1.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Enzyme Activation
  • HEK293 Cells
  • HeLa Cells
  • Humans
  • Hydrogen Peroxide / metabolism
  • Mice
  • Molecular Sequence Data
  • Oxidation-Reduction
  • Oxidative Stress*
  • Phosphorylation
  • Protein Binding
  • Protein Interaction Domains and Motifs
  • Protein Multimerization
  • Protein Processing, Post-Translational
  • Protein Serine-Threonine Kinases / chemistry
  • Protein Serine-Threonine Kinases / genetics
  • Protein Serine-Threonine Kinases / metabolism*
  • Thioredoxins / chemistry
  • Thioredoxins / physiology*
  • Tumor Necrosis Factor-alpha / physiology

Substances

  • Tumor Necrosis Factor-alpha
  • Thioredoxins
  • Hydrogen Peroxide
  • Stk4 protein, mouse
  • Protein Serine-Threonine Kinases