Anti-inflammatory effect of (E)-4-(3,7-dimethylocta-2,6-dienylamino)phenol, a new derivative of 4-nerolidylcatechol

J Pharm Pharmacol. 2013 Jan;65(1):133-41. doi: 10.1111/j.2042-7158.2012.01582.x. Epub 2012 Aug 29.

Abstract

Objectives: We have investigated the anti-inflammatory and antinociceptive effects of (E)-4-(3,7-dimethylocta-2,6-dienylamino)phenol (LQFM-015), which was designed through molecular simplification strategy from 4-nerolidylcatechol.

Methods: The possible anti-inflammatory and antinociceptive effects were assayed on carrageenan-induced paw oedema and pleurisy, acetic acid-induced abdominal writhing and formalin tests in mice.

Key findings: LQFM-015 reduced the activity of PLA₂ enzyme in vitro by 18%. Docking studies into the catalytic site of PLA₂ were used to identify the binding mode of the LQFM-015. LQFM-015 showed a moderate antinociceptive effect, since this compound reduced the number of writhings by approximately up to 40% in the acetic acid-induced pain model; this antinociceptive activity also emerged in the second phase of the formalin-induced pain model (58% of inhibition). The anti-inflammatory action of LQFM-015 was confirmed in acute inflammation models, in which it reduced the formation of oedema to 52.78 ± 8.6 and 46.64 ± 5.2 at the second and third hour of carrageenan-induced paw oedema, respectively. Also in the carrageenan-induced pleurisy model, LQFM-015 reduced the migration of leucocytes by 26.0% and decrease myeloperoxidase activity by 50%. LQFM-015 showed different concentrations to inhibit 50% of isoenzyme cyclooxygenase activity (IC50); COX-1 IC50 = 36 μM) and COX-2 IC50 = 28 μM.

Conclusions: LQFM-015 demonstrated inhibition of both PLA₂ and COX enzymes; thus, the moderate antinociceptive effect of this compound could be attributed to its anti-inflammatory activity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Abdominal Pain / enzymology
  • Abdominal Pain / prevention & control
  • Analgesics / administration & dosage
  • Analgesics / chemistry
  • Analgesics / pharmacology
  • Analgesics / therapeutic use
  • Animals
  • Anti-Inflammatory Agents, Non-Steroidal / administration & dosage
  • Anti-Inflammatory Agents, Non-Steroidal / chemistry
  • Anti-Inflammatory Agents, Non-Steroidal / pharmacology
  • Anti-Inflammatory Agents, Non-Steroidal / therapeutic use*
  • Catalytic Domain
  • Catechols / administration & dosage
  • Catechols / chemistry
  • Catechols / pharmacology
  • Catechols / therapeutic use*
  • Cell Movement / drug effects
  • Dose-Response Relationship, Drug
  • Drug Design*
  • Edema / enzymology
  • Edema / immunology
  • Edema / prevention & control
  • Enzyme Inhibitors / administration & dosage
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology
  • Enzyme Inhibitors / therapeutic use*
  • Lymphocytes / drug effects
  • Lymphocytes / enzymology
  • Lymphocytes / immunology
  • Male
  • Mice
  • Molecular Conformation
  • Molecular Docking Simulation
  • Oxidoreductases / antagonists & inhibitors*
  • Oxidoreductases / metabolism
  • Phospholipase A2 Inhibitors
  • Phospholipases A2 / chemistry
  • Pleurisy / enzymology
  • Pleurisy / immunology
  • Pleurisy / prevention & control
  • Stereoisomerism

Substances

  • (E)-4-(3,7-dimethylocta-2,6-dienylamino)phenol
  • 4-nerolidylcatechol
  • Analgesics
  • Anti-Inflammatory Agents, Non-Steroidal
  • Catechols
  • Enzyme Inhibitors
  • Phospholipase A2 Inhibitors
  • Oxidoreductases
  • Phospholipases A2