Hydrogel-PLGA delivery system prolongs 2-methoxyestradiol-mediated anti-tumor effects in osteosarcoma cells

J Biomed Mater Res A. 2013 Sep;101(9):2491-9. doi: 10.1002/jbm.a.34550. Epub 2013 Jan 27.

Abstract

Osteosarcoma is a bone tumor that affects children and young adults. 2-Methoxyestradiol (2-ME), a naturally occurring estrogen metabolite, kills osteosarcoma cells, but does not affect normal osteoblasts. In order to effectively target osteosarcoma and improve the therapeutic index of the drug 2-ME, we have encapsulated 2-ME in a composite of oligo-(polyethylene glycol) fumarate (OPF) hydrogel and poly (lactic-co-glycolic acid) (PLGA) microspheres and investigated the effect of polymer composition on 2-ME release kinetics and osteosarcoma cell survival. The in vitro study shows that 2-ME can be released in a controlled manner over 21-days. The initial burst releases observed on day 1 were 50% and 32% for OPF and OPF/PLGA composites, respectively. The extended release kinetics show that 100% of the encapsulated 2-ME is released by day 12 from OPF, whereas the OPF/PLGA composites showed a release of 85% on day 21. 2-ME released from the polymers was biologically active and blocked osteosarcoma cell proliferation in vitro. Also, comparison of 2-ME delivery in osteosarcoma cells in culture, shows that direct treatment has no effect after 3 days, whereas polymer-mediated delivery produces anti-tumor effects that could be sustained for 21 days. These findings show that the OPF and PLGA polymeric system may prove to be useful in controlled and sustained delivery of 2-ME and could be further explored in the treatment of osteosarcoma.

Keywords: 2-methoxyestradiol; hydrogel; oligo(polyethylene glycol) fumarate; osteosarcoma; poly (lactic-co-glycolic acid).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • 2-Methoxyestradiol
  • Antineoplastic Agents, Hormonal / administration & dosage
  • Biocompatible Materials
  • Cell Cycle Checkpoints / drug effects
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Delayed-Action Preparations
  • Drug Delivery Systems*
  • Estradiol / administration & dosage
  • Estradiol / analogs & derivatives*
  • Humans
  • Hydrogels
  • Lactic Acid*
  • Materials Testing
  • Microspheres
  • Osteosarcoma / drug therapy*
  • Osteosarcoma / pathology
  • Polyesters
  • Polyethylene Glycols
  • Polyglycolic Acid*
  • Polylactic Acid-Polyglycolic Acid Copolymer

Substances

  • Antineoplastic Agents, Hormonal
  • Biocompatible Materials
  • Delayed-Action Preparations
  • Hydrogels
  • Polyesters
  • oligo(poly(ethylene glycol)fumarate)
  • Polylactic Acid-Polyglycolic Acid Copolymer
  • Polyglycolic Acid
  • Lactic Acid
  • Polyethylene Glycols
  • Estradiol
  • 2-Methoxyestradiol