Bilayer properties of giant magnetic liposomes formed by cationic pyridine amphiphile and probed by active deformation under magnetic forces

Eur Phys J E Soft Matter. 2013 Jan;36(1):9. doi: 10.1140/epje/i2013-13009-0. Epub 2013 Jan 30.

Abstract

We synthesize giant magnetic liposomes by a reverse-phase evaporation method (REV) using a new self-assembling Cationic Pyridine Amphiphile (CPA) derived from 1,4-dihydropyridine as liposome-forming agent and a magnetic ferrofluid based on γ-Fe(2)O(3) nanoparticles. Having in view the potential interest of CPA in targeted transport by magnetic forces, the mechanical elastic properties of such bilayers are here directly investigated in vesicles loaded with magnetic nanoparticles. Bending elastic modulus K(b) ∼ 0.2 to 5k(B)T and pre-stress τ ∼ 3.2 to 12.10(-6) erg/cm(2) are deduced from the under-field deformations of the giant magnetic liposomes. The obtained K(b) values are discussed in terms of A. Wurgers's theory.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Dihydropyridines / chemistry*
  • Hydrophobic and Hydrophilic Interactions*
  • Lipid Bilayers / chemistry*
  • Liposomes / chemistry*
  • Magnetic Fields*
  • Mechanical Phenomena*

Substances

  • Dihydropyridines
  • Lipid Bilayers
  • Liposomes
  • 1,4-dihydropyridine