Effect of alumina on microstructure and compressive strength of a porous silicated hydroxyapatite

J Appl Biomater Funct Mater. 2014 Sep 5;12(2):102-6. doi: 10.5301/JABFM.2012.9772.

Abstract

Purpose: We investigated the effects of alumina addition on microstructure and compressive strength of a porous silicate substituted hydroxyapatite (Si-HA).

Methods: Hydroxyapatite (HA) was synthesized under precipitation conditions and 10 %Wt. of sol-gel derived CaO.P2O5.SiO2 based bioglass (BG) powder was added to HA. Polyurethane foam was used to form a high porous structure with integral porosity of 70%. Phase analysis was performed using XRD and FTIR and the microstructure was studied using SEM.

Results: The results confirmed that the Si-HA was the only formed phase before Al2O3 addition while after addition the presence of silicon-incorporated HA and alumina without any other phases was proved using these analyses.

Conclusions: The porous structures of Si-HA and Al2O3 were synthesized using the replication technique. The compressive strength of porous bioceramics increased with increasing Al2O3 content up to 30 wt% (ANOVA, P<.05).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Oxide / chemistry*
  • Ceramics / chemistry
  • Compressive Strength
  • Durapatite / chemical synthesis
  • Durapatite / chemistry*
  • Microscopy, Electron, Scanning
  • Polyurethanes / chemistry
  • Porosity
  • Silicates / chemistry*
  • Spectroscopy, Fourier Transform Infrared
  • X-Ray Diffraction

Substances

  • Bioglass
  • Polyurethanes
  • Silicates
  • Durapatite
  • Aluminum Oxide