Preparation of graphene/TiO2 composites by nonionic surfactant strategy and their simulated sunlight and visible light photocatalytic activity towards representative aqueous POPs degradation

J Hazard Mater. 2013 Apr 15:250-251:19-28. doi: 10.1016/j.jhazmat.2013.01.069. Epub 2013 Feb 4.

Abstract

A series of graphene/TiO2 composites were fabricated using a single-step nonionic surfactant strategy combined with the solvothermal treatment technique. Their phase structure, morphology, porosity, optical absorption property, as well as composition and structure, were characterized. The as-prepared composites were successfully applied to degrade aqueous persistent organic pollutants (POPs) such as rhodamine B, aldicarb, and norfloxacin in simulated sunlight (λ>320 nm) and visible light (λ>400 nm) irradiation. The degradation mechanism and kinetics of aqueous POPs were studied in detail. The mineralization of aqueous POPs and the recyclability of the composites were also tested in the same condition.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorption
  • Adsorption
  • Aldicarb / isolation & purification
  • Catalysis
  • Graphite / chemistry*
  • Kinetics
  • Microscopy, Atomic Force
  • Microscopy, Electron, Scanning
  • Nitrogen / chemistry
  • Norfloxacin / isolation & purification
  • Photochemistry / methods*
  • Rhodamines / isolation & purification
  • Sunlight
  • Surface-Active Agents / chemistry*
  • Titanium / chemistry*
  • Water Pollutants, Chemical / chemistry
  • X-Ray Diffraction

Substances

  • Rhodamines
  • Surface-Active Agents
  • Water Pollutants, Chemical
  • titanium dioxide
  • Graphite
  • Aldicarb
  • Titanium
  • rhodamine B
  • Norfloxacin
  • Nitrogen