ZnO supported CoFe2O4 nanophotocatalysts for the mineralization of Direct Blue 71 in aqueous environments

J Hazard Mater. 2013 May 15:252-253:171-9. doi: 10.1016/j.jhazmat.2013.02.030. Epub 2013 Feb 26.

Abstract

In this study, an attempt was made to render both the magnetic and photocatalytic properties in a semiconductor material to enhance the efficiency of degradation and recycling possibility of magnetic nanophotocatalysts. CoFe2O4 and CoFe2O4 loaded ZnO nanoparticles were prepared by a simple co-precipitation method and characterized using various analytical tools and in addition to check its visible light assisted photocatalytic activity. CoFe2O4/ZnO nanocatalyst coupled with acceptor, peroxomonosulphate (PMS) showed 1.69-fold enhancement in Direct Blue 71 (triazo dye; DB71) mineralization within 5h. The accomplished enrichment in decolorization was due to the production of more number of non-selective and active free radicals at the catalyst surface.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Azo Compounds / chemistry*
  • Catalysis
  • Cobalt / chemistry
  • Coloring Agents / chemistry*
  • Ferric Compounds / chemistry
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure
  • Microscopy, Electron, Transmission
  • Photochemical Processes
  • Semiconductors
  • Sulfuric Acids / chemistry
  • Water Pollutants, Chemical / chemistry*
  • Zinc Oxide / chemistry*

Substances

  • Azo Compounds
  • Coloring Agents
  • Ferric Compounds
  • Sulfuric Acids
  • Water Pollutants, Chemical
  • Cobalt
  • potassium peroxymonosulfuric acid
  • Direct Blue 71
  • Zinc Oxide