Stereo-selective binding of monoclonal antibodies to the poly-γ-D-glutamic acid capsular antigen of Bacillus anthracis

Mol Immunol. 2013 Oct;55(3-4):337-44. doi: 10.1016/j.molimm.2013.03.010. Epub 2013 Apr 17.

Abstract

Bacillus anthracis is surrounded by an anti-phagocytic capsule that is entirely composed of γ-linked D-glutamic acid (γDPGA). γDPGA is required for virulence and is produced in large quantities following spore germination. We have previously described the isolation of several γDPGA-reactive mAbs. The reagents are effective in both immunoprotection and diagnostic applications. The current work was done to further investigate the specificity of γDPGA-reactive mAbs. The specificity of each mAb was characterized using surface plasmon resonance. Our results indicate that each mAb is stereoselective for binding to D-glutamic acid oligomers, but to varying degrees. In particular, mAb F26G3 is highly selective for γDPGA; alterations in stereochemistry disrupted recognition. These differences in mAb reactivity suggest that binding of γDPGA by mAb F26G3 is more specific than non-directional ionic interactions between a negatively charged antigen and a positively charged antibody.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Antibodies, Monoclonal / chemistry
  • Antibodies, Monoclonal / metabolism*
  • Antibody Affinity*
  • Antibody Specificity
  • Antigen-Antibody Reactions
  • Antigens, Bacterial / chemistry*
  • Bacillus anthracis / chemistry
  • Bacillus anthracis / immunology*
  • Bacterial Capsules / chemistry
  • Bacterial Capsules / immunology*
  • Mice
  • Models, Immunological
  • Polyglutamic Acid / analogs & derivatives*
  • Polyglutamic Acid / chemistry
  • Polyglutamic Acid / immunology
  • Stereoisomerism

Substances

  • Antibodies, Monoclonal
  • Antigens, Bacterial
  • poly(gamma-glutamic acid)
  • Polyglutamic Acid